Financiación FP7 / Fp7 Funds
Resumen: This work reports the fabrication and characterization of Langmuir–Blodgett films of nanoparticles (size 51 ± 10 nm) of the metal organic framework MIL-101(Cr). LB film characterization by SEM, UV–vis, GIXRD, and QCM has shown that the addition of 1 wt % of behenic acid to MOF dispersion allows obtaining dense monolayers at the air–water interface that can be deposited onto solid substrates of different nature with transfer ratios close to 1. Moreover, a QCM-based setup has been built and used for the first time to measure CO2 adsorption isotherms at 303 K on MOF LB films, proving that LB films with MOF masses between 1.2 (1 layer) and 2.3 (2 layers) µg can be used to obtain accurate adsorption values at 100 kPa, similar to those obtained by conventional adsorption methods that require much larger MOF quantities (tens of milligrams).
Idioma: Inglés
DOI: 10.1021/acsami.6b04272
Año: 2016
Publicado en: ACS Applied Materials & Interfaces 8, 25 (2016), 16486-16492
ISSN: 1944-8244

Financiación: info:eu-repo/grantAgreement/ES/DGA/E54
Financiación: info:eu-repo/grantAgreement/ES/DGA/T05
Financiación: info:eu-repo/grantAgreement/EUR/FP7/ERC-2007-2013-608490
Financiación: info:eu-repo/grantAgreement/ES/UZ/JIUZ-2015-CIE-02
Tipo y forma: Article (PostPrint)
Área (Departamento): Química Física (Departamento de Química Física)
Área (Departamento): Física de la Materia Condensada (Departamento de Física de la Materia Condensada)
Área (Departamento): Ingeniería Química (Departamento de Ingeniería Química y Tecnologías del Medio Ambiente)


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Exportado de SIDERAL (2017-02-07-10:39:07)

Este artículo se encuentra en las siguientes colecciones:
Articles > Artículos por área > Física de la Materia Condensada
Articles > Artículos por área > Ingeniería Química
Articles > Artículos por área > Química Física

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 Record created 2016-12-12, last modified 2017-02-07


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