000058435 001__ 58435 000058435 005__ 20170114133551.0 000058435 0247_ $$2doi$$a10.1055/s-0035-1561505 000058435 0248_ $$2sideral$$a96170 000058435 037__ $$aART-2016-96170 000058435 041__ $$aeng 000058435 100__ $$0(orcid)0000-0002-2202-3460$$aMerino Filella, Pedro$$uUniversidad de Zaragoza 000058435 245__ $$aRecent Advances on Asymmetric Nitroso Aldol Reaction 000058435 260__ $$c2016 000058435 5060_ $$aAccess copy available to the general public$$fUnrestricted 000058435 5203_ $$aThe reaction of aromatic nitroso derivatives with enolizable carbonyl compounds (nitroso aldol reaction) to give either a-hydroxyamino or a-aminoxy carbonyl compounds is an important synthetic method. This review illustrates the recent advances in rendering the process regio- and enantioselective as well as catalytic. By employing metal and organic catalysts a range of a-amino (a-oxyamination) and a-hydroxy (a-aminoxylation) carbonyl derivatives can be generated with total regioselectivity and high levels of enantiomeric excess. 000058435 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E10$$9info:eu-repo/grantAgreement/ES/MICINN/CTQ2013-44367-C2-1-P 000058435 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/ 000058435 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion 000058435 700__ $$0(orcid)0000-0003-3433-6701$$aTejero López, Tomás$$uUniversidad de Zaragoza 000058435 700__ $$0(orcid)0000-0001-8355-2289$$aDelso Hernández, José Ignacio$$uUniversidad de Zaragoza 000058435 700__ $$0(orcid)0000-0001-7773-9418$$aMatute Najarro, Rosa Pilar$$uUniversidad de Zaragoza 000058435 7102_ $$15005$$2790$$aUniversidad de Zaragoza$$bDepartamento de Ingeniería Química y Tecnologías del Medio Ambiente$$cTecnologías del Medio Ambiente 000058435 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDepartamento de Química Orgánica$$cQuímica Orgánica 000058435 773__ $$g48, 5 (2016), 653-676$$pSynthesis (Stuttgart)$$tSYNTHESIS-STUTTGART$$x0039-7881 000058435 8564_ $$s874545$$uhttp://zaguan.unizar.es/record/58435/files/texto_completo.pdf$$yPostprint 000058435 8564_ $$s51318$$uhttp://zaguan.unizar.es/record/58435/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint 000058435 909CO $$ooai:zaguan.unizar.es:58435$$particulos$$pdriver 000058435 951__ $$a2017-01-13-15:07:29 000058435 980__ $$aARTICLE