000057746 001__ 57746
000057746 005__ 20170207104153.0
000057746 0247_ $$2doi$$a10.1021/acsami.6b04272
000057746 0248_ $$2sideral$$a95580
000057746 037__ $$aART-2016-95580
000057746 041__ $$aeng
000057746 100__ $$0(orcid)0000-0001-5534-0676$$aBenito Simón, Javier
000057746 245__ $$aLangmuir-Blodgett Films of the Metal-Organic Framework MIL-101(Cr): Preparation, Characterization, and CO2 Adsorption Study Using a QCM-Based Setup
000057746 260__ $$c2016
000057746 5060_ $$aAccess copy available to the general public$$fUnrestricted
000057746 5203_ $$aThis work reports the fabrication and characterization of Langmuir–Blodgett films of nanoparticles (size 51 ± 10 nm) of the metal organic framework MIL-101(Cr). LB film characterization by SEM, UV–vis, GIXRD, and QCM has shown that the addition of 1 wt % of behenic acid to MOF dispersion allows obtaining dense monolayers at the air–water interface that can be deposited onto solid substrates of different nature with transfer ratios close to 1. Moreover, a QCM-based setup has been built and used for the first time to measure CO2 adsorption isotherms at 303 K on MOF LB films, proving that LB films with MOF masses between 1.2 (1 layer) and 2.3 (2 layers) µg can be used to obtain accurate adsorption values at 100 kPa, similar to those obtained by conventional adsorption methods that require much larger MOF quantities (tens of milligrams).
000057746 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E54$$9info:eu-repo/grantAgreement/ES/DGA/T05$$9info:eu-repo/grantAgreement/EUR/FP7/ERC-2007-2013-608490$$9info:eu-repo/grantAgreement/ES/UZ/JIUZ-2015-CIE-02
000057746 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000057746 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000057746 700__ $$0(orcid)0000-0003-1273-2690$$aSorribas Roca, Sara
000057746 700__ $$0(orcid)0000-0003-0271-8713$$aLucas del Pozo, Irene$$uUniversidad de Zaragoza
000057746 700__ $$0(orcid)0000-0003-1512-4500$$aCoronas Ceresuela, Joaquín$$uUniversidad de Zaragoza
000057746 700__ $$0(orcid)0000-0002-3492-6456$$aGascón Sabaté, Ignacio$$uUniversidad de Zaragoza
000057746 7102_ $$12012$$2755$$aUniversidad de Zaragoza$$bDepartamento de Química Física$$cQuímica Física
000057746 7102_ $$12003$$2395$$aUniversidad de Zaragoza$$bDepartamento de Física de la Materia Condensada$$cFísica de la Materia Condensada
000057746 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDepartamento de Ingeniería Química y Tecnologías del Medio Ambiente$$cIngeniería Química
000057746 773__ $$g8, 25 (2016), 16486-16492$$pACS appl. mater. interfaces$$tACS Applied Materials & Interfaces$$x1944-8244
000057746 8564_ $$s4084297$$uhttp://zaguan.unizar.es/record/57746/files/texto_completo.pdf$$yPostprint
000057746 8564_ $$s42290$$uhttp://zaguan.unizar.es/record/57746/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000057746 909CO $$ooai:zaguan.unizar.es:57746$$particulos$$pdriver
000057746 951__ $$a2017-02-07-10:39:07
000057746 980__ $$aARTICLE