000056194 001__ 56194 000056194 005__ 20161006102712.0 000056194 0247_ $$2doi$$a10.1021/acs.energyfuels.5b00459 000056194 0248_ $$2sideral$$a90886 000056194 037__ $$aART-2015-90886 000056194 041__ $$aeng 000056194 100__ $$0(orcid)0000-0002-7767-3057$$aMarrodán Bretón, Lorena$$uUniversidad de Zaragoza 000056194 245__ $$aHigh pressure oxidation of dimethoxymethane 000056194 260__ $$c2015 000056194 5060_ $$aAccess copy available to the general public$$fUnrestricted 000056194 5203_ $$aThe oxidation of dimethoxymethane (DMM) has been studied under a wide range of temperatures (373-1073 K), pressures (20-60 bar) and air excess ratios (¿ = 0.7, 1 and 20), from both experimental and modeling points of view. Experimental results have been interpreted and analyzed in terms of a detailed gas-phase chemical kinetic mechanism for describing the DMM oxidation. The results show that the DMM oxidation regime for 20, 40 and 60 bar is very similar for both reducing and stoichiometric conditions. For oxidizing conditions, a plateau in the DMM, CO and CO2 concentration profiles as a function of the temperature can be observed. This zone seems to be associated with the peroxy intermediate, CH3OCH2O2, whose formation and consumption reactions appear to be important for the description of DMM conversion under high pressure and high oxygen concentration conditions. 000056194 536__ $$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2012-34423 000056194 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/ 000056194 590__ $$a2.835$$b2015 000056194 591__ $$aENGINEERING, CHEMICAL$$b25 / 135 = 0.185$$c2015$$dQ1$$eT1 000056194 591__ $$aENERGY & FUELS$$b33 / 88 = 0.375$$c2015$$dQ2$$eT2 000056194 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion 000056194 700__ $$aRoyo Moros, Eduardo 000056194 700__ $$0(orcid)0000-0001-5426-6486$$aMillera Peralta, Ángela$$uUniversidad de Zaragoza 000056194 700__ $$0(orcid)0000-0002-5420-0943$$aBilbao Duñabeitia, Rafael$$uUniversidad de Zaragoza 000056194 700__ $$0(orcid)0000-0003-4679-5761$$aAlzueta Anía, María Ujué$$uUniversidad de Zaragoza 000056194 7102_ $$15005$$2790$$aUniversidad de Zaragoza$$bDepartamento de Ingeniería Química y Tecnologías del Medio Ambiente$$cTecnologías del Medio Ambiente 000056194 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDepartamento de Ingeniería Química y Tecnologías del Medio Ambiente$$cIngeniería Química 000056194 773__ $$g29, 5 (2015), 3507-3517$$pEnergy fuels$$tENERGY & FUELS$$x0887-0624 000056194 8564_ $$s2083729$$uhttp://zaguan.unizar.es/record/56194/files/texto_completo.pdf$$yPostprint 000056194 8564_ $$s129351$$uhttp://zaguan.unizar.es/record/56194/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint 000056194 909CO $$ooai:zaguan.unizar.es:56194$$particulos$$pdriver 000056194 951__ $$a2016-07-15-11:04:15 000056194 980__ $$aARTICLE